Since the latest Zoiper 5 update, due to changes in the configuration, if you were using any custom STUN options, they have been reverted to the default ones, which may cause exactly the issue which you have described.
Please open Zoiper -> Settings -> Accounts -> your account -> Advanced -> locate the "STUN" option and change it to the STUN recommended by your VOIP provider, or if they do not provide you with one, try setting it to "Disabled", check if this will make any difference.